全文获取类型
收费全文 | 493篇 |
免费 | 29篇 |
国内免费 | 1篇 |
学科分类
工业技术 | 523篇 |
出版年
2023年 | 2篇 |
2022年 | 2篇 |
2021年 | 50篇 |
2020年 | 14篇 |
2019年 | 12篇 |
2018年 | 15篇 |
2017年 | 12篇 |
2016年 | 22篇 |
2015年 | 12篇 |
2014年 | 32篇 |
2013年 | 29篇 |
2012年 | 36篇 |
2011年 | 42篇 |
2010年 | 24篇 |
2009年 | 32篇 |
2008年 | 25篇 |
2007年 | 17篇 |
2006年 | 19篇 |
2005年 | 24篇 |
2004年 | 18篇 |
2003年 | 11篇 |
2002年 | 6篇 |
2001年 | 7篇 |
2000年 | 4篇 |
1999年 | 6篇 |
1998年 | 6篇 |
1997年 | 8篇 |
1996年 | 1篇 |
1995年 | 4篇 |
1994年 | 5篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1990年 | 4篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 5篇 |
1982年 | 2篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1966年 | 1篇 |
1963年 | 1篇 |
1926年 | 1篇 |
排序方式: 共有523条查询结果,搜索用时 15 毫秒
41.
Marcin Pastorczak Michael Wübbenhorst Gustavo Dominguez-Espinosa Lidia Okrasa Marek Pyda Marcin Kozanecki Slawomir Kadlubowski Piotr Ulanski Janusz M. Rosiak Jacek Ulanski 《Polymer》2012,53(1):161-168
The phase transition observed by various methods in poly(vinyl methyl ether)/water systems at around 18 °C has been assigned by some investigators to the pre-melting of water and by others to a glass transition of the polymer. In this study, broadband dielectric spectroscopy and temperature modulated differential scanning calorimetry were used to identify this transition in radiationally crosslinked poly(vinyl methyl ether) hydrogels, as well as to analyse sub-zero relaxation processes in such a three-phase (polymer/ice/liquid water) system. The process at 18 °C was related to the pre-melting of water induced by the segmental motions of the polymer; however, it was seen to be one transition due to the cooperative motions of both compounds. The atypical (two regimes) temperature dependence of the segmental motion process was observed and was related to confinement of the polymer chains between ice clusters below approximately ?24 °C; furthermore, the main dielectric process of hexagonal ice was identified and a Maxwell-Wagner effect was observed. 相似文献
42.
Ofelia G. Meza‐Márquez Tzayhrí Gallardo‐Velázquez Guillermo Osorio‐Revilla Lidia Dorantes‐Álvarez 《International Journal of Food Science & Technology》2012,47(11):2342-2351
Mid‐infrared spectroscopy (FT‐Mid IR) coupled with multivariate analysis was used to predict clenbuterol in beef meat, liver and kidney. A SIMCA model was also developed to discriminate between pure (beef meat, liver and kidney) and spiked with clenbuterol samples (beef meat‐clenbuterol, liver‐clenbuterol and kidney‐clenbuterol). The best models to predict clenbuterol concentrations were obtained using the partial least squares algorithm (PLS) with a R2 > 0.9 and SEC and standard error of prediction <0.296 and 0.324, respectively. The SIMCA model used to discriminate pure and spiked with clenbuterol samples showed 100% correct classification rate. Methods detection limit was 2 μg kg?1. FT‐Mid IR coupled with chemometrics could be a simple and rapid screening tool for monitoring clenbuterol in beef meat, liver and kidney implicated in food poisoning. This method could be use for screening purposes. 相似文献
43.
44.
This paper documents the development of an empirically-basedsystem implemented in Prolog that automatically resolves severalkinds of anaphora in Spanish texts. These are pronominalreferences, surface-count anaphora, one-anaphora and ellipticalzero-subject constructions (i.e., sentences that omit theirpronominal subject). The resolution is based onrepresentations resulting from either partial or full parsing. Thesystem developed can also work on the output of a POStagger or with different dictionaries, without changing thegrammar. This grammar represents the syntactic information of eachlanguage by means of the Slot Unification Grammar formalism. The different kinds of information used for anaphora resolution in full and partial parsing are shown, as wellas evaluation results. The system has been adapted toEnglish texts, obtaining encouraging results that prove that itcan be applied with only a very few refinements to other languagesas well as Spanish and English. In addition, the differencesbetween English and Spanish anaphora are noted. 相似文献
45.
46.
Fastenau Philip S.; Denburg Natalie L.; Domitrovic Lidia A. 《Canadian Metallurgical Quarterly》1997,28(1):32
Clinicians sometimes worry that the administration of intentional memory tests early in a clinical battery might artificially enhance performance on subsequent incidental memory tests, with possible differential effects for younger vs. older adults. Eighty-one healthy adults (ages 30–80) were blindly assigned to 1 of 2 testing conditions (incidental followed by intentional and vice versa). Contrary to the concerns of some, administration of intentional tests prior to incidental tests did not affect performance on any measures, and there was no interaction with age. Order of administration did not affect performance in older or younger adults. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
47.
Improvement in the oxidation resistance of SUS304 stainless steel was accomplished by electrodeposition of La in a molten salt. The electrolysis of La was conducted using a potentiostatic-polarization method in an equimolar NaCl–KCl melt containing 3.5 mol. LaF 3 at 1023 K. Observation of the specimen surface after polarization at –1.8 V (vs. Ag/Ag+ (0.1)) for 0.18 ks showed that La particles were uniformly dispersed on the surface. The oxidation resistance of the electrodeposited stainless steel was significantly improved as compared with the untreated stainless steel. The scale formed on the untreated stainless steel after oxidation was thick and consisted of Fe2O3 and Fe3O4, whereas the scale formed on the elecrodeposited stainless steel was extremely thin, and mainly consisted of Cr2O3. 相似文献
48.
Irina Pozdnyakova Alexandra Navrotsky Lidia Shilkina Larisa Reznitchenko 《Journal of the American Ceramic Society》2002,85(2):379-384
Thermodynamics of the Na1−x Li x NbO3 system is investigated by high-temperature drop-solution calorimetry in molten 3Na2 O–4MoO3 solvent at 973 K. Standard molar enthalpies of formation are derived. The estimated heats of transition between hypothetical and stable structures, lithium niobate and perovskite for NaNbO3 and vice versa for LiNbO3 are −6 kJ/mol and −10 kJ/mol, respectively. X-ray diffraction studies at room temperature showed for 0 ≤ x ≤ 0.14 there are three phases based on different ordering of the perovskite type lattice: orthorhombic with a quadrupled reduced perovskite cell at 0 ≤ x ≤ 0.02, orthorhombic with a doubled reduced perovskite cell at 0.015 ≤ x ≤ 0.14, and rhombohedral at 0.08 ≤ x ≤ 0.13. There are two two-phase (morphotropic) regions with coexistence of the two orthorhombic phases at 0.015 ≤ x ≤ 0.02 and with the second orthorhombic phase coexisting with the rhombohedral phase at 0.08 ≤ x ≤ 0.13. A reproducible anomaly in specific heat at ∼600 K, not reported previously, has been observed in pure NaNbO3 . Heat-capacity measurements confirm a phase transition at 553 K for 0.07 ≤ x ≤ 0.09. With increasing lithium concentration, a gradual disappearance of high-temperature phase transitions associated with tilting of oxygen octahedra has been observed. 相似文献
49.
50.
Waste management systems are a non-negligible source of greenhouse gases. In particular, methane and carbon dioxide emissions occur in landfills due to the breakdown of biodegradable carbon compounds operated on by anaerobic bacteria. The conventional possibilities of reducing the greenhouse effect (GHE) from waste landfilling consists in landfill gas (LFG) flaring or combustion with energy recovery in reciprocating engines. These conventional treatments are compared with three innovative possibilities: the direct LFG feeding to a fuel cell (FC); the production of a hydrogen-rich gas, by means of steam reforming and CO2 capture, to feed a stationary FC; the production of a hydrogen-rich gas, by means of steam reforming and CO2 capture, to feed a vehicle FC. The comparison is carried out from an environmental point of view, calculating the specific production of GHE per unit mass of waste disposed in landfill equipped with the different considered technologies. 相似文献